Gigolo currently defaults to using 'gvfs-open'. However, for at least a few gvfs version 'gvfs-open' is no longer installed. Judging by the commit log, it has been replaced by 'gio' tool, with its 'gio open' subcommand.
Fixed. https://git.xfce.org/apps/gigolo/commit/?id=fb63ddf0fa4ed93789366aefb7a2a2b44e919386