thunar-volman should try to automount only in the active session. Right now all thunar-volman processes trying to mount (race condition) and thus blocking each other and popping unwanted authentication request in the wrong sessions. As a simple workaround one can place the following script in /usr/local/bin (assuming that logind is running on the system): #!/bin/bash if [ $(loginctl user-status $USER | grep -c 'State: active') -gt 1 ]; then exec /usr/bin/thunar-volman $@ fi But IMO the check for the active session should be done by thunar-volman.
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